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ChemInform Abstract: Preparation and Crystal Structure of Barium Caesium Undecaphosphide- Ammonia (1/11) BaCsP11×11 NH3.

✍ Scribed by N. KORBER; J. DANIELS

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Preparation and Crystal Structure of Barium Caesium Undecaphosphide-Ammonia (1/11) BaCsP11•11 NH3. -The structure of the title compound is determined by single crystal XRD. (III) crystallizes in the monoclinic space group P21/a with Z = 8. The Cs+ ions are coordinated by the undecaphosphatrishomocubane anions P3-11 in such a way that infinite 1∞(CsP2-11) chains are formed which are separated by Ba(NH3)2+n cations (n = 8 and 9). Only one Ba-P contact is observed. -(KORBER,

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