ChemInform Abstract: Preferential Site Occupation in the Quasi-Ternary Channel Compounds TlCr5S8-ySey (1 ≤ y ≤ 7) Introducing Anisotropic Variations of Interatomic Interactions: A Systematical Study of Their Crystal Structures.

Preferential Site Occupation in the Quas

Preferential Site Occupation in the Quasi-Ternary Channel Compounds TlCr5S8–ySey (1 ≤ y ≤ 7) Introducing Anisotropic Variations of Interatomic Interactions: A Systematical Study of their Crystal Structures

✍ Wolfgang Bensch; Bernd Sander; Christian Näther; Inke Jeß; Oliver Helmer 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 205 KB 👁 1 views

The results of single crystal X-ray investigations of the quasi-ternary channel compounds TlCr 5 S 8±y Se y (1 ≤ y ≤ 7) show a linear increase of the unit cell volume with increasing Se content as expected for a solid solution. The successive occupation of the four distinct chalcogene sites by Se, h