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ChemInform Abstract: Prearranged Glycosides. Part 13. Intramolecular Mannosylations of Glucosamine, Galactose, Mannose, and Rhamnose Derivatives via Prearranged Glycosides.

โœ Scribed by Gregor Lemanski; Thomas Ziegler

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
32
Category
Article
ISSN
0931-7597

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Prearranged Glycosides, Part 13, Intramo
Prearranged Glycosides, Part 13, Intramolecular Mannosylations of Glucosamine, Galactose, Mannose, and Rhamnose Derivatives via Prearranged Glycosides
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A series of prearranged glycosides 4, 9, 14, 16, 22, 28, 33, 41, and 46, having a benzyl-protected 1thiomannosyl donor linked through its position 6 via malonate and succinate tethers to various positions of glucosamine, galactose, mannose, and rhamnose acceptors, were prepared and cyclized to the c

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A series of prearranged glycosides 5, 17, 23, 28, 37, and 41, having a benzyl-protected 1-thiomannosyl donor linked through its positions 2, 3, 4, and 6 via succinate and malonate tethers, respectively, to positions 2, 3, and 6 of a benzyl glucopyranoside acceptor, were prepared by condensation of t