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ChemInform Abstract: Powerful Kinetic Diastereoselection in Ruthenium-Catalyzed Ring-Closing Metathesis of (Homoallyl)vinylcyclopropanes.

✍ Scribed by Guy C. Lloyd-Jones; Martin Murray; Rosie A. Stentiford; Paul A. Worthington


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
31
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable via the β€œReferences” option.


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Homoallyl-substituted vinyl cyclopropanes 1a-c, which are readily prepared by reaction of allylindium reagents with Ξ±,Ξ²-unsaturated ketones and aldehydes, undergo Ru-catalysed RCM reactions with Grubbs catalyst to give [4.1.0]bicyclooct-2-ene (norcarene) type bicyclic products. Noncyclisable 'trans'

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v