Homoallyl-substituted vinyl cyclopropanes 1a-c, which are readily prepared by reaction of allylindium reagents with Ξ±,Ξ²-unsaturated ketones and aldehydes, undergo Ru-catalysed RCM reactions with Grubbs catalyst to give [4.1.0]bicyclooct-2-ene (norcarene) type bicyclic products. Noncyclisable 'trans'
ChemInform Abstract: Powerful Kinetic Diastereoselection in Ruthenium-Catalyzed Ring-Closing Metathesis of (Homoallyl)vinylcyclopropanes.
β Scribed by Guy C. Lloyd-Jones; Martin Murray; Rosie A. Stentiford; Paul A. Worthington
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v