The dispiroketones 46 have been synthesized and rearranged by treatment with acids yielding the bicyclic enone 36 under kinetic control and the [3.3.3]propellane 37 under thermodynamic control. The corresponding alcohols 10-12 all yield the [3.3.3]propeUane 41. The rearrangement of [7,7-D2)-12 to [8
β¦ LIBER β¦
ChemInform Abstract: Polyspiranes. Part 23. Cascade Rearrangements. Part 18. Synthesis and Rearrangement of Dispiro(3.1.3.2)-, Dispiro(3.0.3.3)- and Dispiro(3.0. 4.2)undecanes - New Entries to (3.3.3)Propellanes.
β Scribed by L. FITJER; A. KANSCHICK; M. MAJEWSKI
- Book ID
- 112021119
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 35 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0931-7597
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