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ChemInform Abstract: Polyspiranes. Part 23. Cascade Rearrangements. Part 18. Synthesis and Rearrangement of Dispiro(3.1.3.2)-, Dispiro(3.0.3.3)- and Dispiro(3.0. 4.2)undecanes - New Entries to (3.3.3)Propellanes.

✍ Scribed by L. FITJER; A. KANSCHICK; M. MAJEWSKI


Book ID
112021119
Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
26
Category
Article
ISSN
0931-7597

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The dispiroketones 46 have been synthesized and rearranged by treatment with acids yielding the bicyclic enone 36 under kinetic control and the [3.3.3]propellane 37 under thermodynamic control. The corresponding alcohols 10-12 all yield the [3.3.3]propeUane 41. The rearrangement of [7,7-D2)-12 to [8

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v