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ChemInform Abstract: Polymeric Metal Complex Catalyzed Enantioselective Epoxidation of Olefins.

✍ Scribed by Pradeep K. Dhal; Binod B. De; Swaminathan Sivaram

Publisher
John Wiley and Sons
Year
2010
Weight
24 KB
Volume
33
Category
Article
ISSN
0931-7597

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Polymeric catalysts for chemo- and enant
Polymeric catalysts for chemo- and enantioselective epoxidation of olefins: New crosslinked chiral transition metal complexing polymers
✍ Binod B. De; Braj B. Lohray; Swaminathan Sivaram; Pradeep K. Dhal πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 177 KB πŸ‘ 2 views

Polymeric analogs of well-known chiral Mn(III)-salen complexes were synthesized and were used as recyclable catalysts for asymmetric epoxidation of olefins. For this purpose two different monomers, 2 and 3, bearing chiral Mn(III)-salen moieties were synthesized. The monomer 3 carries a bulky substit