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ChemInform Abstract: Polymer-Supported Highly Enantioselective Catalyst for Nitro-Michael Addition: Tuning Through Variation of the Number of H-Bond Donors and Spacer Length.

✍ Scribed by Lital Tuchman-Shukron; Moshe Portnoy

Publisher: John Wiley and Sons
Year: 2009
Weight: 29 KB
Volume: 40
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200929027

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Abstract

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Polymer-Supported Highly Enantioselectiv

Polymer-Supported Highly Enantioselective Catalyst for Nitro-Michael Addition: Tuning through Variation of the Number of H-Bond Donors and Spacer Length

✍ Lital Tuchman-Shukron; Moshe Portnoy 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 256 KB 👁 1 views

## Abstract magnified image Two series of polymer‐bound bifunctional organocatalysts, based on chiral diamine scaffolds, were prepared by solid‐phase synthesis. The series, incorporating a single hydrogen bond donor carbamate functionality, was notably more enantioselective in the Michael reaction