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ChemInform Abstract: Polyaniline Supported Cobalt(II)-Salen Catalyst: One-Pot Synthesis of . beta.-Phenylisoserine Derivatives from Cinnamoyl Amide.

✍ Scribed by B. C. DAS; J. IQBAL

Publisher: John Wiley and Sons
Year: 2010
Weight: 30 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199732160

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✦ Synopsis

Polyaniline Supported Cobalt(II)-Salen Catalyst: One-Pot Synthesis of . beta.-Phenylisoserine Derivatives from Cinnamoyl Amide.

-A novel one-pot conversion of the cinnamoyl amides (I) to β-phenylisoserine derivatives (III) is described. Thus, conversion of (I) to epoxides by a PSCScatalyzed oxidation followed by ring opening with the anilines (II) leads to the targets in a highly diastereoselective manner. -(DAS, B.

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