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ChemInform Abstract: Plyers-Shaped Diamines. Part 2. 3-Amino-2,4-cyclogranatane Diastereomers — A Study of Influence of Structure on the Properties of Diamines.

✍ Scribed by E. VILSMAIER; T. HERWECK; U. BERGSTRAESSER


Book ID
101869845
Publisher
John Wiley and Sons
Year
2010
Weight
26 KB
Volume
29
Category
Article
ISSN
0931-7597

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Plyers-shaped diamines II. 3-Amino-2,4-c
✍ Elmar Vilsmaier; Thomas Herweck; Uwe Bergsträßer 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 736 KB

3-Amino-2,4-cyclogranatane 313-and 3a-diastereomers can be synthesized from the corresponding 313-carbonitriles by a kine~ically and a thermodynamically controlled reductive decyanation, respectively. Comparison of both diastereomers with respect to basicity, ionization potentials and behaviour towa