Plyers-shaped diamines II. 3-Amino-2,4-c
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Elmar Vilsmaier; Thomas Herweck; Uwe Bergsträßer
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Article
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1998
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Elsevier Science
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French
⚖ 736 KB
3-Amino-2,4-cyclogranatane 313-and 3a-diastereomers can be synthesized from the corresponding 313-carbonitriles by a kine~ically and a thermodynamically controlled reductive decyanation, respectively. Comparison of both diastereomers with respect to basicity, ionization potentials and behaviour towa