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ChemInform Abstract: Photostimulated Reductive Cyclization of o-Nitrophenylazo Dyes Using Sodium Hydroxide in Isopropyl Alcohol. A New Synthesis of 2-Aryl-2H-benzotriazoles.

✍ Scribed by Woonphil Baik; Chang Hyun Yoo; Sangho Koo; Hern Kim; Yong Hyun Hwang; Byeong Hyo Kim; Seok Woo Lee


Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis


Photostimulated Reductive Cyclization of o-Nitrophenylazo Dyes

Using Sodium Hydroxide in Isopropyl Alcohol. A New Synthesis of 2-Aryl-2H-benzotriazoles.

-With a view to environmental problems, the new efficient title method for the preparation of plastic additives (II) has a crucial advantage by use of a nonmetallic reducing agent. The photostimulated reductive cyclization proceeds through the formation of N-oxides as intermediates.