ChemInform Abstract: Photorearrangement of the ortho-Cycloadduct of 6-Chloro-1,3-dimethyluracil to Benzene Through [π4s + π2a] Photocycloaddition.

✍ Scribed by K. OHKURA; Y. NOGUCHI; K. SEKI

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 32 KB
• Volume: 29
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199816144

✦ Synopsis

Photorearrangement of the ortho-Cycloadduct of 6-Chloro-1,3dimethyluracil to Benzene Through [π4s + π2a] Photocycloaddition.

-The reaction pathway for formation of hydrogen chloride adducts such as (III) and (IV) derived from the photoreaction of title compound (I) and the mechanism involving the initial ortho-cycloaddition and the successive intramolecular photo-Diels-Alder reaction are presented. -(OHKURA, K.;