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ChemInform Abstract: Photoinduced Valence Isomerization of 2-Trifluoroacetyl-3- phenylbicyclo(2.2.1)hepta-2,5-diene (I).

โœ Scribed by M. V. PROSKURINA; A. G. KAZ'MIN; A. YU. ZENOVA; S. A. LERMONTOV; A. A. BORISENKO; N. S. ZEFIROV


Book ID
112039434
Publisher
John Wiley and Sons
Year
2010
Weight
26 KB
Volume
27
Category
Article
ISSN
0931-7597

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Photoinduced addition of nucleophiles to
โœ Paul G. Gassman; Kurt D. Olson ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 251 KB

The l-cyanonaphthalene photosensitized addition of water and methanol to the cation-radical of bicyclo[2.2.1]hepta-2,5-diene is described. Recently, we demonstrated that nucleophiles could be added across strained carbon-carbon sigma bonds in photosensitized reactions which are readily interpreted