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ChemInform Abstract: Photoinduced Molecular Transformations. Part 158. An Total Synthesis of (.+-.)-Methyl Piperitol: An Unsymmetrically Substituted 2,6-Diaryl- 3,7-dioxabicyclo(3.3.0)octane Lignan.

✍ Scribed by K. ORITO; T. SASAKI; H. SUGINOME

Book ID: 112027412
Publisher: John Wiley and Sons
Year: 2010
Weight: 34 KB
Volume: 27
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199606268

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Photoinduced molecular transformations.

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ChemInform Abstract: An Alternative Diastereospecific Approach to (.+-.)-Samin and 2,6-Diaryl-3,7-dioxabicyclo[3.3.0]octane [Furanofuran] Lignans Based on the Ireland—Claisen Rearrangement of Unsaturated Oxa-macrolides.

✍ H. M. HULL; R. G. JONES; D. W. KNIGHT 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 39 KB 👁 2 views

An Alternative Diastereospecific Approach to (±)-Samin and 2,6-Diaryl-3,7-dioxabicyclo[3.3.0]octane [Furanofuran] Lignans Based on the Ireland-Claisen Rearrangement of Unsaturated Oxa-macrolides. -Ireland-Claisen rearrangement of the macrolide (II) gives stereospecifically the tetrahydrofurancarbox