ChemInform Abstract: Photochemical Generation of Radical Species from α-Stannyl Ethers and Their Reaction with Conjugate Enones.

✍ Scribed by Tetsuhiro Mikami; Manabu Harada; Koichi Narasaka

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 33 KB
• Volume: 30
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199940054

✦ Synopsis

Photochemical Generation of Radical Species from α-Stannyl Ethers and Their Reaction with Conjugate Enones.

-The title reaction of ethers, e.g. (I), with enones like (II) and (VI) occurs in the presence of photosensitizers to afford the corresponding addition products (III) and (VII). A mechanism is discussed.