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ChemInform Abstract: Photoaddition of Benzoxazole-2-thiones with Alkenes.

✍ Scribed by T. NISHIO; Y. MORI; I. IIDA; A. HOSOMI


Book ID
112035567
Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
27
Category
Article
ISSN
0931-7597

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Photoaddition of N-Acylbenzoxazole-2-thiones to Alkenes. -Benzoxazoles (I) and (V) undergo photoaddition to alkenes in a regioselective manner to give addition products of type (III)/(VIII) and/or the unexpected thietanes (IV)/(VI) depending on the substituents both on the benzoxazole nitrogen and

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## Abstract Photoaddition reactions of benzoxazole‐2‐thiones **1** with cycloalkenes **2** and heteroaromatics **3** were examined. Irradiation of __N__‐acylbenzoxazole‐2‐thiones **1a** and **1b**, and 3‐(methoxycarbonyl)‐ and 3‐(phenoxycarbonyl)benzoxazole‐2(3__H__)‐thiones (**1f** and **1h**, res