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ChemInform Abstract: Phosphinoyl Radicals: Structure and Reactivity. A Laser Flash Photolysis and Time-Resolved ESR Investigation.

โœ Scribed by Steffen Jockusch; Nicholas J. Turro


Book ID
101876894
Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
30
Category
Article
ISSN
0931-7597

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## Abstract **A variety** of differently substituted 6โ€ and 7โ€arylchromenes such as that depicted undergo photoinduced C๏ฃฟO bond cleavage to yield colored __o__โ€quinonoid intermediates. A combined analysis of ฮผsโ€“ms (laser flash) and realโ€time kinetic data show that the __o__โ€quinonoid intermediates