ChemInform Abstract: Phosphine-Mediated Domino Benzannulation Strategy for the Construction of Highly Functionalized Multiaryl Skeletons.
β Scribed by Peizhong Xie; You Huang; Ruyu Chen
- Book ID
- 115553830
- Publisher
- John Wiley and Sons
- Year
- 2012
- Weight
- 59 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0931-7597
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Strategy for the Construction of Functionalized Five-and Six-Membered Carbocycles. -Conjugate addition of the Grignard reagents (II) and (IV) to the nitro olefins (I) leads to the intermediate formation of nitronates, which are trapped as silyl nitronates and subsequently cyclized by intramolecular