ChemInform Abstract: Phosphine Ligand Triggered Oxidative Decarbonylative Homocoupling of Aromatic Aldehydes: Selectively Generation Biaryls and Diarylketones.

✍ Scribed by Luo Yang; Tieqiang Zeng; Qi Shuai; Xiangyu Guo; Chao-Jun Li

• Book ID: 102062511
• Publisher: John Wiley and Sons
• Year: 2011
• Weight: 39 KB
• Volume: 42
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.201124088

✦ Synopsis

Abstract

Novel rhodium‐catalyzed oxidative decarbonylative homocoupling of aryl aldehydes (I) in the presence of triphenylphosphine affords biaryls (II) as main products and diaryl ketones as by‐products.