## Abstract Depending on the nature of educts, the PBu~3~‐catalyzed reaction of allylic carbonates with enones allows efficient formation of cascade [3 + 2] cyclization—allylic alkylation, [3 + 2] cyclization, or [2 + 2 + 1] annulations products.
✦ LIBER ✦
ChemInform Abstract: Phosphine-Catalyzed [4 + 1] Annulation Between α,β-Unsaturated Imines and Allylic Carbonates: Synthesis of 2-Pyrrolines.
✍ Scribed by Junjun Tian; Rong Zhou; Haiyun Sun; Haibin Song; Zhengjie He
- Publisher
- John Wiley and Sons
- Year
- 2011
- Weight
- 42 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
The title reaction provides a new, highly efficient, and diastereoselective approach to trans‐substituted pyrrolines of type (III) and fused pyrrolines like (V).
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