✦ LIBER ✦

ChemInform Abstract: Phase Relations in the MgMoO4-Mg3V2O8 System and Crystal Structure of Mg2.54V1.08Mo0.92O8.

✍ Scribed by X. WANG; C. L. STERN; K. R. POEPPELMEIER

Publisher: John Wiley and Sons
Year: 2010
Weight: 31 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199713011

No coin nor oath required. For personal study only.

✦ Synopsis

Phase Relations in the MgMoO4-Mg3V2O8 System and Crystal Structure of Mg2.54V1.08Mo0.92O8.

-In the phase diagram of the pseudobinary title system, established by XRD and DTA methods, a solid solution Mg2.5+xV1+2xMo1-2xO8 (-0.05 . ltoreq. x ≤ 0.05) is found at 1100 • C in air. Single crystals of the title composition are grown from the Mg-V-Mo oxide flux and characterized by single crystal XRD. In the structure ( orthorhombic, Pnma, Z = 6) V and Mo cations remain in their highest oxidation state. Charge neutrality associated with the variation of the V/Mo ratio is balanced by the Mg cation concentration in the crystal. -(WANG,

📜 SIMILAR VOLUMES

ChemInform Abstract: The Na/V/P/N(C2H5)3

ChemInform Abstract: The Na/V/P/N(C2H5)3/H2O System at 473 K and the New Open Framework Structure of the Vanadium Phosphate Phase Nav(((4+4-wV5+1+w)O9)(PO4)2). times.(PO4)x×(OH)y×zH2O (with v = 2.8 to 4.0, w = -0.1 to 1.1, x = 0 to 0.2, y = 0 to 2.1, and z = 7 to 10).

✍ M. SCHINDLER; W. JOSWIG; W. H. BAUR 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 35 KB

ChemInform Abstract: Phase Formation in

ChemInform Abstract: Phase Formation in the Na2MoO4—MgMoO4—Cr2 (MoO4)3 System.

✍ I. Yu. Kotova; N. M. Kozhevnikova 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 35 KB

ChemInform Abstract: Phase Relations in

ChemInform Abstract: Phase Relations in the System AlF3-RbF.

✍ R. CHEN; Q. ZHANG 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB 👁 1 views

ChemInform Abstract: Phase Relations in

ChemInform Abstract: Phase Relations in the Ca2Ta2O7—Nd3TaO7 System.

✍ A. P. Pivovarova; V. I. Strakhov; Yu. N. Smirnov 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB

ChemInform Abstract: Phase Relations in

ChemInform Abstract: Phase Relations in the CaTa2O6—LaTa3O9 System.

✍ A. P. Pivovarova; V. I. Strakhov; Yu. N. Smirnov 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 36 KB

ChemInform Abstract: Phase Relations in

ChemInform Abstract: Phase Relations in the NbO2—MnO System.

✍ V. P. Mar'evich; V. M. Chumarev 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 1 views