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ChemInform Abstract: Perfluoroalkyl-Chalcogenation of Alkynes.

โœ Scribed by Y. UEDA; M. KANAI; K. UNEYAMA


Book ID
112020909
Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
26
Category
Article
ISSN
0931-7597

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Perfluoroalkyl-chalcogenation of olefins
โœ Kenji Uneyama; Masatomi Kanai; Kouichi Kitagawa ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 40 KB

Perfluoroalkyl-chalcogenation of olefins has been performed by the reaction of chalcogenide anions with perfluoroalkylhalides (IV-X) in the presence of olefins. Chalcogenide anion cleaves reductively the carbon-halogen bond of Bf-X, generating perfluoroalkyl radicals which undergo addition to C=C bo