Perfluoroalkyl-chalcogenation of olefins
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Kenji Uneyama; Masatomi Kanai; Kouichi Kitagawa
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Article
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1991
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Elsevier Science
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English
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Perfluoroalkyl-chalcogenation of olefins has been performed by the reaction of chalcogenide anions with perfluoroalkylhalides (IV-X) in the presence of olefins. Chalcogenide anion cleaves reductively the carbon-halogen bond of Bf-X, generating perfluoroalkyl radicals which undergo addition to C=C bo