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ChemInform Abstract: PdII-Catalyzed C—H Functionalization of Indoles and Pyrroles Assisted by the Removable N-(2-Pyridyl)sulfonyl Group: C2-Alkenylation and Dehydrogenative Homocoupling.

✍ Scribed by Alfonso Garcia-Rubia; Beatriz Urones; Ramon Gomez Arrayas; Juan Carlos Carretero

Publisher
John Wiley and Sons
Year
2010
Weight
73 KB
Volume
42
Category
Article
ISSN
0931-7597

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PdII-Catalysed CH Functionalisation of I
PdII-Catalysed CH Functionalisation of Indoles and Pyrroles Assisted by the Removable N-(2-Pyridyl)sulfonyl Group: C2-Alkenylation and Dehydrogenative Homocoupling
✍ Alfonso García-Rubia; Beatriz Urones; Ramón Gómez Arrayás; Juan Carlos Carretero 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 402 KB

## Abstract The easily installed and removed __N__‐(2‐pyridyl)sulfonyl group exerts complete C2 regiocontrol over the Pd^II^‐catalysed CH alkenylation of indoles and pyrroles, affording the corresponding products in good isolated yields (typically ≥70 %). A remarkable feature of this catalyst syst