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ChemInform Abstract: Pd-NHC Catalyzed Biaryl Coupling by Direct C—H Activation — A Novel Strategy for the Synthesis of Dibenzocyclooctane Lignans.

✍ Scribed by Ericsson David Coy; Luis Enrique Cuca; Michael Sefkow

Publisher
John Wiley and Sons
Year
2011
Weight
30 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

Title compounds (III) and its trans‐diastereomer are synthesized starting from the corresponding lignans isolated from leaves of Ocotea macrophylla via biaryl coupling reaction.

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ChemInform Abstract: Pd(II)-Catalyzed or
ChemInform Abstract: Pd(II)-Catalyzed ortho-Arylation of 6-Arylpurines with Aryl Iodides via Purine-Directed C—H Activation: A New Strategy for Modification of 6-Arylpurine Derivatives.
✍ Hai-Ming Guo; Li-Li Jiang; Hong-Ying Niu; Wei-Hao Rao; Lei Liang; Run-Ze Mao; De 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 31 KB 👁 1 views

## Abstract The reaction proceeds selectively as a monoarylation in ortho position even with an excess of aryl iodides.