ChemInform Abstract: Pd- and Cu-Catalyzed Selective Arylation of Benzotriazole.
β Scribed by I. P. BELETSKAYA; D. V. DAVYDOV; M. MORENO-MANAS
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 28 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Pd-and Cu-Catalyzed Selective Arylation of Benzotriazole. -The Pd-catalyzed reaction of benzotriazole with aryl halides is investigated. Best results are achieved under the conditions shown. The N-1 arylated benzotriazoles (III) (15 examples) are obtained in high regioselectivity. -(BELETSKAYA,
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## Abstract Reaction of various unsubstituted or monosubstituted arenes with benzamides applies Nβfluorobenzenesulfonimide as a bystanding oxidant to provide the corresponding biaryls with high paraβselectivity.