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ChemInform Abstract: PAs3S3 Cage as a New Building Block in Copper Halide Coordination Polymers.

✍ Scribed by Patrick Schwarz; Joachim Wachter; Manfred Zabel


Publisher
John Wiley and Sons
Year
2011
Weight
27 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

Coordination polymers from (III) and copper halides are obtained by interdiffusion techniques between solvents of different polarity and characterized by Raman spectroscopy and single crystal XRD.


πŸ“œ SIMILAR VOLUMES


P4S3 and P,Pβ€² or N,Nβ€² Donors as Competit
✍ Andreas Biegerl; Dmitry Piryazev; Manfred Scheer; Joachim Wachter; Alexander Vir πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons 🌐 English βš– 809 KB

The synthesis and characterization of hybrid polymers combining organic P,PЈ (dppe) or N,NЈ (pyrazine) ligands and inorganic donors (P 4 S 3 ) as cross-linkers between copper(I) halide aggregates is described. As a simple model system the reaction of a mixture of P 4 S 3 , PEt 3 , and CuX (X = Cl, B