ChemInform Abstract: Palladium(0)/Indium Iodide Mediated Allylations of Electrophiles Generated from the Hydrolysis of Eschenmoser′s Salt: One-Pot Preparation of Diverse Carbocyclic Scaffolds.

Palladium(0)/indium iodide-mediated ally

Palladium(0)/indium iodide-mediated allylations of electrophiles generated from the hydrolysis of Eschenmoser’s salt: one-pot preparation of diverse carbocyclic scaffolds

✍ Cara Cesario; Marvin J. Miller 📂 Article 📅 2010 🏛 Elsevier Science 🌐 French ⚖ 327 KB

A formyl equivalent was generated in situ from Eschenmoser's salt in aqueous THF and was reacted with an allylindium species. Acylnitroso-derived hetero-Diels-Alder adducts and related allyl acetates were shown to be substrates for Pd(0)/InI-mediated allylations of formaldehyde-related species to pr