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ChemInform Abstract: Palladium(0)-Catalyzed Substitution of Allylic Substrates in Perfluorinated Solvents.

✍ Scribed by Robert Kling; Denis Sinou; Gianluca Pozzi; Agnes Choplin; Francoise Quignard; Stefan Busch; Sabine Kainz; Daniel Koch; Walter Leitner

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: The Stereochemical
ChemInform Abstract: The Stereochemical Dichotomy in Palladium(0)- and Nickel(0)-Catalyzed Allylic Substitution.
✍ C. N. FARTHING; P. KOCOVSKY πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 40 KB

The Stereochemical Dichotomy in Palladium(0)-and Nickel(0)-Catalyzed Allylic Substitution. -In contrast to the known inversion-inversion steric pathway of allylic esters like (I), the corresponding acetate (IV), containing a phosphinous amide moiety, gives on treatment with malonate (II) in the pre