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ChemInform Abstract: Palladium-Induced Intramolecular Coupling Reactions of Some Alkenyl(o-iodobenzyl)silanes.

โœ Scribed by Zhu Teng; Reinhart Keese


Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
30
Category
Article
ISSN
0931-7597

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Palladium-Induced Intramolecular Couplin
โœ Zhu Teng; Reinhart Keese ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 108 KB

The first examples for the formation of siloles by intramolecular Heck-type cyclizations are reported. Upon treatment with [PdCl 2 (PPh 3 )], the (o-iodobenzyl)vinylsilanes 4a and 4c give the siloles 5a and 5c as well as the vinyl-transfer products 6a and 6c (Scheme 2), respectively. Under CO pressu