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ChemInform Abstract: Palladium-Catalyzed β Arylation of Carboxylic Esters.

✍ Scribed by Alice Renaudat; Ludivine Jean-Gerard; Rodolphe Jazzar; Christos E. Kefalidis; Eric Clot; Olivier Baudoin

Publisher
John Wiley and Sons
Year
2011
Weight
64 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

The lithium enolates formed in situ from carboxylic acid esters by treatment with LiNCy~2~ are arylated at the β‐position instead at the more common α‐position by aryl halides bearing at the ortho‐position electronegative substituents.

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