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ChemInform Abstract: Palladium-Catalyzed Synthesis of Enantiomerically Pure α-Substituted Allylboronic Esters and Their Addition to Aldehydes.

✍ Scribed by Enrique Fernandez; Joerg Pietruszka; Wolfgang Frey

Publisher
John Wiley and Sons
Year
2010
Weight
64 KB
Volume
41
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Palladium-Catalyzed
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✍ W. OPPOLZER; A. PIMM; B. STAMMEN; W. E. HUME 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 37 KB

Palladium-Catalyzed Intramolecular Cyclization of Olefinic Propargylic Carbonates and Application to the Diastereoselective Synthesis of Enantiomerically Pure (-)-α-Thujone. -Pd/P(2-furyl)3 catalyzed title reactions afford intermediate palladium( alkenyl)bicyclo(3.1.0)hexanes, which can be trapped