ChemInform Abstract: Palladium-Catalyzed Synthesis of 1,3,4-Alkatrien-2-yldihydrofurans from 2,3-Allenylacetylacetates and Propargylic Carbonates and Their Application to Synthesize Polysubstituted Dihydrofurylcyclopentenones.
β Scribed by Wei Shu; Shengming Ma
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 26 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0931-7597
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Palladium(II)-Catalyzed 1,4-Oxidation of 2-Aryl-1,3-cyclohexadienes. Application to the Synthesis of (Β±)-Epibatidine and Analogues. -1,4-Chloroacetoxylation of arenes (I) in the presence of palladium(II) catalyst gives cis-cyclohexenes (III) with high regio-and stereoselectivity. These products are