ChemInform Abstract: Palladium-Catalyzed Substitution of Ketone or Aldehyde Bearing Aryl Triflates by Amines or Amides.
β Scribed by Xiaochun Tao; Chunya Dai; Xiongjie Cao; Lisheng Cai; Victor W. Pike
- Publisher
- John Wiley and Sons
- Year
- 2009
- Weight
- 27 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0931-7597
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Bismuth(III) Chloride or Triflate-Catalyzed Dienophilic Activity of . alpha.-Ethylenic Aldehydes and Ketones. -BiCl3 and especially Bi(OTf)3 are found to be efficient catalysts for (4 + 2) cycloadditions with Ξ±-carbonyl ethylenic dienophiles. They show higher reactivity and selectivity than Sc-, Ti
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