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ChemInform Abstract: Palladium-Catalyzed Oxidative Arylalkylation of Activated Alkenes: Dual C—H Bond Cleavage of an Arene and Acetonitrile.

✍ Scribed by Tao Wu; Xin Mu; Guosheng Liu

Book ID
112043975
Publisher
John Wiley and Sons
Year
2012
Weight
43 KB
Volume
43
Category
Article
ISSN
0931-7597

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Palladium-Catalyzed Oxidative Arylalkyla
Palladium-Catalyzed Oxidative Arylalkylation of Activated Alkenes: Dual CH Bond Cleavage of an Arene and Acetonitrile
✍ Tao Wu; Xin Mu; Prof. Dr. Guosheng Liu 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 379 KB

The oxidative difunctionalization of alkenes is a powerful strategy for the synthesis of various organic compounds. [1] Recent studies have demonstrated that palladium-catalyzed oxidative transformations, such as aminooxygenation, [2] diamination, [3] and dioxygenation [4] of alkenes, can be used ef

Palladium-Catalyzed Oxidative Arylalkyla
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✍ Tao Wu; Xin Mu; Prof. Dr. Guosheng Liu 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 361 KB

Not one but two: The title reaction proceeds through the dual C-H bond cleavage of both aniline and acetonitrile. The reaction affords a variety of cyano-bearing indolinones in excellent yield. Mechanistic studies demonstrate that this reaction involves a fast arylation of the olefin and a rate-dete