ChemInform Abstract: Palladium-Catalyzed Intramolecular Selenocarbamoylation of Allenes with Carbamoselenoates: A New Entry to α,β-Unsaturated Lactams.
✍ Scribed by Masashi Toyofuku; Erika Murase; Hiroyuki Nagai; Shin-ichi Fujiwara; Tsutomu Shin-ike; Hitoshi Kuniyasu; Nobuaki Kambe
- Publisher
- John Wiley and Sons
- Year
- 2009
- Weight
- 31 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0931-7597
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## Abstract For Abstract see ChemInform Abstract in Full Text.
Palladium-Catalyzed Intramolecular Alkyne-α,β-Unsaturated Carbonyl Coupling. A Formal Synthesis of (+)-Pilocarpine. -Pd-catalyzed enyne coupling of (E) or (Z) alkynoates (I) or (III) provides the alkenyl substituted lactones (II) highly stereoselectively. After esterification with (+)-dimethyltart
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