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ChemInform Abstract: Palladium-Catalyzed Dehydrogenation of Benzylic Alcohols in Molten Ammonium Salts, a Recyclable System.

โœ Scribed by Benjamin Ganchegui; Sandrine Bouquillon; Francoise Henin; Jacques Muzart


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
33
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Direct Carbonylatio
โœ Y.-S. LIN; A. YAMAMOTO ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 36 KB ๐Ÿ‘ 1 views

The carbonylation of benzyl alcohol (Ia) with carbon monoxide in the presence of a HI-[Pd(PPh 3 ) 4 ] catalytic system proceeds smoothly to give the phenylacetic acid (IIIa) as main product. The same acid can be obtained by carbonylation of benzyl formate, dibenzyl ether and benzyl phenylacetate. Th