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ChemInform Abstract: Palladium-Catalyzed Cyclization of α-Hydroxy Allylic Acetates: A Formal Synthesis of (.+-.)-Swainsonine.

✍ Scribed by Roderick W. Bates; Mark R. Dewey; Chi H. Tang; Shahidah bte Safii; Yanhan Hong; Jolyn Ke Hui Hsieh; Pei Shan Siah

Publisher
John Wiley and Sons
Year
2011
Weight
28 KB
Volume
43
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

The Pd‐catalyzed cyclization of allylic acetate (I) is directed by the OH group to give a trans‐substituted piperidine.

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ChemInform Abstract: Palladium(0)-Cataly
ChemInform Abstract: Palladium(0)-Catalyzed Domino Cyclization—Carbonylation of Alkenyl-Allenyl-Allylic Acetate.
✍ Takayuki Doi; Masaru Takasaki; Sadahiro Nakanishi; Arata Yanagisawa; Keiji Yamam 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 1 views

Palladium(0)-Catalyzed Domino Cyclization-Carbonylation of Alkenyl-Allenyl-Allylic Acetate. -Optimum reaction conditions for the domino cyclization-carbonylation of title acetate (I) are presented, involving five and six consecutive C-C bond forming steps. Palladium-catalyzed reaction of title aceta