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ChemInform Abstract: Palladium-Catalyzed Cyclization and Cyclization—Carbonylation of Unsaturated C-Glycoside Derivatives. The Importance of Relative Stereochemistry.

✍ Scribed by C. W. HOLZAPFEL; L. MARAIS


Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
30
Category
Article
ISSN
0931-7597

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Palladium(0)-Catalyzed Domino Cyclization-Carbonylation of Alkenyl-Allenyl-Allylic Acetate. -Optimum reaction conditions for the domino cyclization-carbonylation of title acetate (I) are presented, involving five and six consecutive C-C bond forming steps. Palladium-catalyzed reaction of title aceta