Palladium-Catalyzed Cyanation of Hindered, Electron-Rich Aryl Triflates by Zinc Cyanide. -The Pd-catalyzed cyanation of 2methoxyphenyl triflate (I) as model for hindered, electron-rich aryl triflates, using zinc cyanide is evaluated. Application of the optimized conditions to the triflate (IV) allo
ChemInform Abstract: Palladium-Catalyzed Cyanation of Aryl Triflates
β Scribed by Yi-Zhong Zhu; Chun Cai
- Publisher
- John Wiley and Sons
- Year
- 2009
- Weight
- 24 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0931-7597
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Palladium-Catalyzed Amination of Aryl Triflates. -The first examples of palladium-catalyzed amination of readily available aryl triflates is presented. Best yields of amines are obtained using electronically neutral or electron-rich aryl triflates. -(WOLFE,