ChemInform Abstract: Palladium-Catalyzed Coupling Reactions of 1-Bromoadamantane with Styrenes and Arenes.

✍ Scribed by S. BRAESE; B. WAEGELL; A. DE MEIJERE

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 32 KB
• Volume: 29
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199823088

✦ Synopsis

Palladium-Catalyzed Coupling Reactions of 1-Bromoadamantane with Styrenes and Arenes.

-A new convenient preparation of bridgehead derivatives of adamantane is presented. The Heck-type coupling products (III) are obtained with styrenes, while the reaction with arenes affords the adamantyl-substituted arenes (V).