ChemInform Abstract: Palladium-Catalyzed Coupling Reaction of Acylzirconocene Chlorides with Hypervalent Iodonium Salts: Synthesis of Aryl-Substituted Ketones.
β Scribed by Suk-Ku Kang; Seok-Keun Yoon
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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Reductive Coupling Reaction of Hypervalent Iodonium Salts Catalyzed by Palladium-Zinc System. -The Pd-catalyzed ligand coupling of various diaryl-or alkynyl(phenyl) iodonium salts in the presence of diethylzinc provides biaryls (II) or dialkynes (IV), resp., under mild conditions. -(KANG, S.-K.