Palladium-Mediated Cyclization on Carbohydrate Templates. Part 2. Synthesis of Enantiopure Tricyclic Compounds. -A full account of previously briefly reported studies on the applications and limitations of intramolecular Heck-type reactions in carbohydrate chemistry is given. -(NGUEFACK,
ChemInform Abstract: Palladium-Catalyzed Cascade Reactions of Unsaturated Carbohydrate Derivatives. Synthesis of Enantiopure Tricyclic Compounds.
β Scribed by C. W. HOLZAPFEL; L. MARAIS
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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Palladium-Mediated Cyclization on Carbohydrate Templates. Part 1. Synthesis of Enantiopure Bicyclic Compounds. -It is shown that various 4-O-bromoalkenyl-β2-glycopyranosides and their N-and C-analogues undergo an unexpected palladium-mediated Heck-type cyclization under Jeffery's conditions. The con
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