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ChemInform Abstract: Palladium-Catalyzed Carbonylative Reaction of 1-(2,2-Dibromovinyl)-2-alkenylbenzene and Carbon Monoxide, with Phenol or Alcohol.

✍ Scribed by Shengqing Ye; Jie Wu

Publisher: John Wiley and Sons
Year: 2012
Weight: 50 KB
Volume: 43
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201213112

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✦ Synopsis

Palladium-Catalyzed Carbonylative Reaction of 1-(2,2-Dibromovinyl)-2-alkenylbenzene and Carbon Monoxide, with Phenol or Alcohol. -The addition of molecular sieves is highly effective for the reaction of phenols, whereas no advantage is observed in the case of alcohol substrates [cf. (IV)]. In all cases, the (E)-isomer is formed exclusively.

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