ChemInform Abstract: Palladium-Catalyzed Borylation of Aryl Arenesulfonates with Dialkoxyboranes.
β Scribed by Miki Murata; Takeshi Oda; Yosuke Sogabe; Hirofumi Tone; Takeshi Namikoshi; Shinji Watanabe
- Publisher
- John Wiley and Sons
- Year
- 2012
- Weight
- 33 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
Borylation of arenesulfonates (I) with dialkoxyborane (II) proceeds in the presence of a combination of Pd(dba)~2~ and a phosphanoferrocene derivative as a versatile catalyst system to afford arylboronates (III) in good yields.
π SIMILAR VOLUMES
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## Abstract The protocol gives alkylboronates in good yield and stereoselectivity and requires only minimal amounts of reactants.