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ChemInform Abstract: Palladium-Catalyzed Asymmetric Conjugate Addition of Aryl—Metal Species

✍ Scribed by Andrey Gutnov

Publisher
John Wiley and Sons
Year
2009
Weight
15 KB
Volume
40
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Palladium Catalyzed
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Palladium Catalyzed Addition of Carbon Pronucleophiles to Conjugated Enynes. -A new, catalytic route to the synthesis of differently substituted allenes is developed by addition of cyano-based carbon nucleophiles to conjugated enynes. Pd2(dba)3•CHCl3/dppf is found to be the best catalytic system fo