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ChemInform Abstract: Palladium Acetate Catalyzed Oxidative Aromatization of Methylenecyclopropanes.

โœ Scribed by Min Jiang; Yin Wei; Min Shi

Publisher
John Wiley and Sons
Year
2010
Weight
23 KB
Volume
41
Category
Article
ISSN
0931-7597

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โœฆ Synopsis

Abstract

Isopropenylbiaryl derivatives are formed under palladium catalysis through dehydrogenated rearrangement of alkenes (I).

๐Ÿ“œ SIMILAR VOLUMES

Palladium Acetate Catalyzed Oxidative Ar
Palladium Acetate Catalyzed Oxidative Aromatization of Methylenecyclopropanes
โœ Min Jiang; Yin Wei; Min Shi ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 141 KB

## Abstract Isopropenylbiaryl derivatives were produced in moderate to good yields at high temperature from the reaction of methylenecyclopropanes (MCPs) **1** in the presence of palladium acetate under ambient atmosphere by tandem intramolecular Cโ€“H and Cโ€“C bond activation and aromatization throug