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ChemInform Abstract: Oxocarbenium Ion Cyclizations under Non-Acidic Conditions: Synthesis of Tetrahydropyran Analogues of the Pseudomonic Acids.

✍ Scribed by Noshena Khan; Haiyun Xiao; Bo Zhang; Xuhong Cheng; David R. Mootoo

Publisher: John Wiley and Sons
Year: 2010
Weight: 31 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199941258

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✦ Synopsis

Oxocarbenium Ion Cyclizations under Non-Acidic Conditions: Synthesis of Tetrahydropyran Analogues of the Pseudomonic Acids. -C 5 -Alkylated 1,2-O-isopropylidene furanosides such as (I) undergo a completely stereoselective reaction with iodonium ions to lead to tetrahydropyran subunits of pseudomonic acids.

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