ChemInform Abstract: Oxidative Activation in Aromatic Substitutions. Reactions of N,N-Dimethylanilines with Secondary Anilines Promoted by Thallium Triacetate.

✍ Scribed by Francesco Ciminale; Antonella Ciardo; Salvatore Francioso; Angelo Nacci

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 30 KB
• Volume: 30
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199935092

✦ Synopsis

Oxidative Activation in Aromatic Substitutions. Reactions of N,N-Dimethylanilines with Secondary Anilines Promoted by Thallium Triacetate.

-The title reactions offer a novel oxidatively activated aromatic substitution affording 1,4-benzenediamine derivatives like (III). It proceeds well with the anisidine (I) but with the anilines (IV) and (V) limitations are observed. -(CIMINALE, FRANCESCO; CIARDO, ANTONELLA;