ChemInform Abstract: Oxidation of Terminal Olefins by Dioxygen in the Presence of PdII (NH3)x/CuII/LiI/Cl- or PdII (or Pd0)/Zeolites/CuII/LiI/Cl- Systems and a Coreducer (Ethanol).

Oxidation of Terminal Olefins by Dioxyge

Oxidation of Terminal Olefins by Dioxygen in the Presence of PdII(NH3)x-CuII-LiI-Cl− or PdII (or Pd0)/Zeolites/CuII-LiI-Cl− Systems and a Coreducer (Ethanol)

✍ Ourida Mohammedi; Farid Chemat; Jean-Marie Brégeault 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 288 KB 👁 2 views

Simple ammonia complexes {cis-[PdCl 2 (NH 3 ) 2 ], [Pd(NH 3 ) 4 ]-cooxidation products. Chorohydridopalladium species are key intermediates in the isomerization of 1-alkenes; it Cl 2 or [Pd(NO 2 ) 2 (NH 3 ) 2 ]} with copper(II) chloride and LiCl or Pd II (or Pd 0 ) inserted into zeolite (faujasite Y