ChemInform Abstract: Oxidation of Secondary Alkanols with the System Cerium Ammonium Nitrate—Lithium Bromide into Ketones, α-Bromo Ketones, and α,α′-Dibromo Ketones.

✍ Scribed by G. I. Nikishin; L. L. Sokova; N. I. Kapustina

• Publisher: John Wiley and Sons
• Year: 2011
• Weight: 36 KB
• Volume: 42
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.201109053

✦ Synopsis

Oxidation of Secondary Alkanols with the System Cerium Ammonium Nitrate--Lithium Bromide into Ketones, α-Bromo Ketones, and α,α'-Dibromo Ketones. -The selectivity of the oxidation reaction depends only on the molar ratio of the reagents. Appropriate conditions for the selective formation of the corresponding Ketones, α-bromo ketones or dibromo ketones are established. -(NIKISHIN, G. I.;