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ChemInform Abstract: Oxidation of Organic Sulfides to Sulfoxides by Nitric Acid Catalyzed by FeBr3 and (FeBr3)2(DMSO)3.

✍ Scribed by A. R. SUAREZ; L. I. ROSSI; S. E. MARTIN

Book ID
112022672
Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
26
Category
Article
ISSN
0931-7597

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The binary system Fe(NO 3 ) 3 -FeBr 3 is a very efficient catalyst for the selective air-oxidation of sulfides to sulfoxides. Since the oxidation is selective, it may be applied to any type of dialkyl and alkyl aryl sulfide, as well as to substrates of biological interest. It develops in mild condit